全文获取类型
收费全文 | 85281篇 |
免费 | 12943篇 |
国内免费 | 8938篇 |
专业分类
化学 | 58192篇 |
晶体学 | 938篇 |
力学 | 5625篇 |
综合类 | 770篇 |
数学 | 10449篇 |
物理学 | 31188篇 |
出版年
2024年 | 83篇 |
2023年 | 1654篇 |
2022年 | 1796篇 |
2021年 | 2743篇 |
2020年 | 3286篇 |
2019年 | 3118篇 |
2018年 | 2732篇 |
2017年 | 2552篇 |
2016年 | 3831篇 |
2015年 | 3892篇 |
2014年 | 4673篇 |
2013年 | 6154篇 |
2012年 | 7450篇 |
2011年 | 7673篇 |
2010年 | 5274篇 |
2009年 | 5086篇 |
2008年 | 5376篇 |
2007年 | 4776篇 |
2006年 | 4409篇 |
2005年 | 3847篇 |
2004年 | 3125篇 |
2003年 | 2447篇 |
2002年 | 2304篇 |
2001年 | 1995篇 |
2000年 | 1749篇 |
1999年 | 1850篇 |
1998年 | 1525篇 |
1997年 | 1313篇 |
1996年 | 1320篇 |
1995年 | 1186篇 |
1994年 | 1122篇 |
1993年 | 984篇 |
1992年 | 862篇 |
1991年 | 761篇 |
1990年 | 621篇 |
1989年 | 546篇 |
1988年 | 411篇 |
1987年 | 385篇 |
1986年 | 342篇 |
1985年 | 349篇 |
1984年 | 225篇 |
1983年 | 198篇 |
1982年 | 165篇 |
1981年 | 137篇 |
1980年 | 101篇 |
1979年 | 67篇 |
1978年 | 71篇 |
1977年 | 67篇 |
1975年 | 65篇 |
1973年 | 63篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
11.
Saqib Kamal Arif I. Inamdar Kuan-Ru Chiou Batjargal Sainbileg Muhammad Usman Jenq-Wei Chen Tzuoo-Tsair Luo Michitoshi Hayashi Chen-Hsiung Hung Wen-Feng Liaw Kuang-Lieh Lu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(30):e202103905
The dielectric properties of coordination polymers has been a topic of recent interest, but the role of different functional groups on the dielectric properties of these polymers has not yet been fully addressed. Herein, the effects of electron-donating (R=NH2) and electron-withdrawing (R=NO2) groups on the dielectric behavior of such materials were investigated for two thermally stable and guest-free Zn-based coordination polymers, [Zn(L1)(L2)]n ( 1 ) and [Zn(L1)(L3)]n ( 2 ) [L1=2-(2-pyridyl) benzimidazole (Pbim), L2=5-aminoisophthalate (Aip), and L3=5-nitroisophthalate (Nip)]. The results of dielectric studies of 1 revealed that it possesses a high dielectric constant (κ=65.5 at 1 kHz), while compound 2 displayed an even higher dielectric constant (κ=110.3 at 1 kHz). The electron donating and withdrawing effects of the NH2 and NO2 substituents induce changes in the polarity of the polymers, which is due to the inductive effect from the aryl ring for both NO2 and NH2. Theoretical results from density functional theory (DFT) calculations, which also support the experimental findings, show that both compounds have a distinct electronic behavior with diverse wide bandgaps. The significance of the current work is to provide information about the structure-dielectric property relationships. So, this study promises to pave the way for further research on the effects of different functional groups on coordination polymers on their dielectric properties. 相似文献
12.
13.
为解决深度学习在图像水印算法中计算量大且模型冗余的问题,提高图像水印算法在抵抗噪声、旋转和剪裁等攻击时的鲁棒性,提出基于快速神经网络架构搜索(neural architecture search,NAS)的鲁棒图像水印网络算法。通过多项式分布学习快速神经网络架构搜索算法,在预设的搜索空间中搜索最优网络结构,进行图像水印的高效嵌入与鲁棒提取。首先,将子网络中线性连接的全卷积层设置为独立的神经单元结构,并参数化表示结构单元内节点的连接,预先设定结构单元内每个神经元操作的搜索空间;其次,在完成一个批次的数据集训练后,依据神经元操作中的被采样次数和平均损失函数值动态更新概率;最后,重新训练搜索完成的网络。水印网络模型的参数量较原始网络模型缩减了92%以上,大大缩短了模型训练时间。由于搜索得到的网络结构更为紧凑,本文算法具有较高的时间性能和较好的实验效果,在隐藏图像时,对空域信息的依赖比原始网络更少。对改进前后的2个网络进行了大量鲁棒性实验,对比发现,本文算法在CIFAR-10数据集上对抵抗椒盐噪声和旋转、移除像素行(列)等攻击优势显著;在ImageNet数据集上对抵抗椒盐高斯噪声、旋转、中值滤波、高斯滤波、JPEG压缩、裁剪等攻击优势显著,特别是对随机移除行(列)和椒盐噪声有较强的鲁棒性。 相似文献
14.
Zhengcheng Wang Shangyan Zhou Wei Liao Qian Zhou Meida Chen Jin Long Prof. Qingmei Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(66):e202201987
The designs of efficient and inexpensive Pt-based catalysts for methanol oxidation reaction (MOR) are essential to boost the commercialization of direct methanol fuel cells. Here, the highly catalytic performance PtFe alloys supported on multiwalled carbon nanotubes (MWCNTs) decorating nitrogen-doped carbon (NC) have been successfully prepared via co-engineering of the surface composition and electronic structure. The Pt1Fe3@NC/MWCNTs catalyst with moderate Fe3+ feeding content (0.86 mA/mgPt) exhibits 2.26-fold enhancement in MOR mass activity compared to pristine Pt/C catalyst (0.38 mA/mgPt). Furthermore, the CO oxidation initial potential of Pt1Fe3@NC/MWCNTs catalyst is lower relative to Pt/C catalyst (0.71 V and 0.80 V). Benefited from the optimal surface compositions, the anti-corrosion ability of MWCNT, strong electron interaction between PtFe alloys and MWCNTs and the N-doped carbon (NC) layer, the Pt1Fe3@NC/MWCNTs catalyst presents an improved MOR performance and anti-CO poisoning ability. This study would open up new perspective for designing efficient electrocatalysts for the DMFCs field. 相似文献
15.
Hao Lu Xiaodong Wang Hang Wang Andong Zhang Xinming Zheng Na Yu Zheng Tang Xinjun Xu Yahui Liu Ya-Nan Chen Zhishan Bo 《中国科学:化学(英文版)》2022,65(3):594-601
Three nonfused ring electron acceptors (NFREAs) TTC6,TT-C8T and TT-TC8 were purposefully designed and synthesized.The molecular geometry can be adjusted by the steric hindrance of lateral substituents.According to the DFT calculations,from TTC6 to TT-C8T and TT-TC8,planarity of the molecular backbone is gradually improved,accompanying with the enhancing of intramolecular charge transfer effect.As for TT-TC8,the two phenyl substituents are almost perpendicular to the molecular backbone,which endues the acceptor with good solubility and suppresses it to form over-aggregation.Multidirectional regular molecular orientation and closer molecular stacking are formed in TT-TC8 film.As a result,TT-TC8 based devices afford the highest PCE of 13.13%,which is much higher than that of TTC6 (4.41%) and TT-C8T (10.42%) and among the highest PCE values based on NFREAs. 相似文献
16.
17.
根据教育部颁布的《普通高中物理课程标准(2017年版)》,在上海市物理教育教学基地(上海高校“立德树人”人文社会科学重点研究基地)的大力支持下,由上海市教育委员会组织编写的上海高中物理非统编教材进行了正式使用前的试教试用活动,此教材是在上海高中物理“二期课改”教材的基础上全面改写而成的.单元教学设计已成为当前教学设计的焦点问题,以《物理·必修》(第三册)静电场单元为例,详细阐述了“教学问题链”的设计理念,希望与广大一线教师交流试教试用的心得与反思,推动新课改课堂转型. 相似文献
18.
Zhang Ya-Li Han Rong-Sheng Chen Liang 《International Journal of Theoretical Physics》2021,60(4):1384-1398
International Journal of Theoretical Physics - In this work, we give an analytical derivation of the reduced density matrix between two qubits in a cavity field, which is described by the quantum... 相似文献
19.
20.
Geometriae Dedicata - We show that an n-dimensional surface whose entropy is close to that of an n-dimensional plane is close in Hausdorff distance to some n-dimensional plane at every scale.... 相似文献